Background / Requirement
The manufacturing of sunblock creams and lotions has been on a steady increase in recent years as a result of increased awareness on the effects of ultra-violet rays (UV) and exposure to skin. Increased awareness has created the requirement for specialty products such as water-resistant formulas, infant formulas, and increased sun protection factors (SPF) formulas. Manufacturing techniques play an important role in adapting to the changing market to meet the requirements of the consumer while maximizing the performance of the ingredients.
Manufacturing sunblock creams and lotions involve either oil-in-water or water-in-oil emulsions. Typical ingredients include emollients (smoothing agents), lubricants, emulsifying and thickening agents, perfume, color, preservatives and UV filters and absorbers such as titanium dioxide or zinc oxide. In the case of the latter ingredients, UV protection is directly related to the dispersion quality and particle size on the UV filters and absorbers.
Most sunblock products are produced in the following manner:
Powdered ingredients, such as cetyl alcohol and stearic acid are typically dispersed into the oil phase. The water phase is prepared separately, containing emulsifiers and stabilizers (Carbomers, Cellulose Gums, Hydrocolloids)
The oil phase and water phase are then mixed to form an emulsion. Depending on the formulation, some applications may require heating 110 - 185°F (45 - 85°C)
Depending on the formulation, the UV filters and absorbers are supplied as a powder and can be dispersed into either the water or oil phase before or after the emulsion is formed
Mixing is continued until the end product is homogeneous.
- Additives designed to thicken the product are by nature liable to form agglomerates, which a conventional mixer cannot easily break down
Partially hydrated ingredients can build up on the vessel walls and mixer shaft
Emulsions are not easily formed with conventional agitators even with the addition of heat. The addition of emulsifiers, stabilizers and certain additives can reduce SPF of the lotions. For this reason it is important to use the minimal ingredients required to create a stable emulsion
UV absorbers are supplied in micronized form. Conventional agitators are not capable of breaking the components down to their individual particle sizes
Long batch times and often additional equipment is required to achieve a satisfactory consistency
Significant air entrainment occurs as a result of the incorporation of powders from the liquid surface.
Quadro's Approach to Manufacturing Sunblocks and Creams
Quadro recommends the combined use of a Ytron® ZC Powder Disperser and a Ytron® Jet Mixer. The ZC is designed to disperse extremely difficult to wet powders in a single pass without lumps or 'fisheyes'.
The powder incorporation can be completed during the addition of water or oil phase to the processing vessel or in a recirculation loop from the vessel. Powder incorporation is achieved by the presence of significant vacuum in the reactor generated by a liquid ring seal created between the rotor and stator. The powders are then subjected to enough shear to provide a complete dispersion in a single pass before returning to the processing vessel. The second phase is added to the vessel and the Jet Mixer provides a good top to bottom turnover of the tank ingredients to ensure a homogeneous blend and a finished emulsion.
Quadro Ytron® ZC Powder Disperser Advantages
- Single-pass processing ensures repeatable, consistent product batch to batch
- Improved dispersion of micronized oxides results in better SPF
- Lump free lotions ensures maximum yield of raw materials and results in better SPF
- Premixing of powdered ingredients is not necessary
- Rapid mixing times
- Formation of a stable emulsion.